If I ever do a full stinger restore, yes, I would go with a synthetic material and not wood. For the time being, my 2 recent repairs have used wood, pretty much for convenient sake.
The challenge to using the synthetics (like divinycell) is that it is crazy expensive. So, the challenge is to find something at a reasonable cost that is compatible with the resins that you will be using to 'glass' everything together.
The newer wood that is KDAT plywood (that JnG mentioned), like Perma Panel or Greenwood XL, is better than the wood of old, and many manufacturers have switched to using KDAT PT Plywood. My issue with using wood is that it still wants to absorb water. So, it will absorb whatever it can during its life cycle. As to whether that causes rot or not is another story.
A synthetic core to the structural components will not readily want to absorb water, so it is better than wood in that regard.