not sure what you are reading. however PVA is mold release. you can use it a month later if you want. it then washes off with a simple hose and water.
if you are using wax, apply another 2-3 layers as unless you rub in wax, your not getting enough coverage.
styrene is basically the thinner used in gel. that wont seal it up against the air like you need.
This is what i read from 'FiberGlast.com'; a large supplier of gel coat products. Im willing to believe what your saying though as I've seen incorrect information when it comes to (my expertise) Automotive and industrial painting online before
"
#13 PVA Release Film can also be used as an air inhibitor. Simply spray the PVA onto the gel coat and allow to cure. The timing of the application of the PVA is important. The gel coat needs to crosslink with itself right from the start without interference from the atmosphere. Applying the PVA right after you spray the gel coat will also trap styrene in the gel coat and prevent it from evaporating, thus aiding the curing process. Once the gel coat has cured, the PVA can then be washed off with soap and water."
Spraying the wax infused styrene made it maybe a little firmer in my test location but still ever so slightly tacky as before. Seemed like putting very little on was a must as I had one drip of the styrene wax that hung on under the boat and it actually reactivated the gel coat and made a wrinkle in the finish. One thing the extra wax did though is made the boat a pain to sand, cut, and buff as my sand pads would immediately fill up with a bunch of wax. It actually ended up being much easier to sand and cut the areas where i didn't apply a coat of wax. It seemed like after i took off the very top layer of the finish, it was no longer tacky. Maybe i was just feeling the wax on the surface when i felt that it was a tiny bit tacky but while being hard as a rock? In conclusion, the only reason i would see that anyone would apply pure wax infused styrene after the fact is if maybe they forgot to add it to their final coat and also dont have enough gelcoat to apply another coat.