I've learned a few things the hard way over the past few years with solar and LiFePO4 (LFP) batteries.
- Expect about 65% of the rated watt output from a solar panel . . . A 5 watt panel is not going to charge a decent sized battery any time soon (weeks). Since LFP batteries can take a lot of current, a small solar panel can't really 'get ahead of the game', and the battery drags down the voltage of the solar panel. I think you are seeing that . . .
- LiFePO4 batteries should wake up at 11.5 volts (+/-) and then go up from there, if they have gone into low voltage protection mode.
- I have found the 14.6 volt chargers can bring the LiFePO4 into over voltage protection mode, which will then give a reading of about 12 volts until they 'wake up'. I try to disconnect my chargers when the batteries get into the high 13 volt range (13.8 ish).
- It is OK to trickle charge LFP batteries, but they don't need it as much as lead-acid. Trickle charging should be in the 13.5 volt range.
- Got any parasitic draws on your boat to worry about? You'll want the solar to be able to keep ahead of those.
- Now that the sun has gone lower in the sky, and the daylight hours are less, I am finding that my 100 watt panel (20 watts per battery) is not able to keep ahead of the game and I have to supplement with shore power. This may be a concern for late-season boating.