Re: Charging boat while on the highway.
I'd be REALLY careful just blindly connecting them together. You absolutely need to know two very key pieces of information, don't even think of doing it until you know those for sure.
a) how big of an alternator in the f250? (and how much spare capacity)
b) How much of a draw are you going to be putting on it.
Once you know those, that will tell you if its safe/possible, and how to do it. Keep in mind those fridges probably have some serious electrical draw if they both kick on, and unless you plan on burning the whole rig down when you overheat a wire, you are going to have some fairly large wire going directly to the battery of the truck.
just as an example, here is a tiny 3 way rv fridge. It draws ~12 amps on 12 volts.
https://www.makariosrv.com/products/Norcold-N260.3-3-Way-Refrigerator.html
So two of those are going to be sucking down 24 amps.
Now head on over to a wire size calculator...
http://beta.circuitwizard.bluesea.com/
I used 24 amps and 60 feet (has to go from your battery in the truck to the battery/fridges in the boat, plus turns, so size the length to whatever you think might be close. I have a feeling 60ft isn't too far off depending on boat) Keep in mind that length also must include a ground from the boat's negative ground to the trailer.
Anyway, 60 feet, 24 amps, some other standard variables, and it spit out a wire size of 2/0 gauge. (that is HUGE wire, but if you plan on doing it safely and not lighting the whole rig on fire, that is the only way)
The better option as far as wiring would be concerned is put a decent inverter in the truck cab, and then run an extension cord at 120v to the boat. Its far easier to transport higher voltage without needing massive wire. You lose a little in the inverter, as well the fridge being slightly less efficient on 12 volt, so you will need a little more spare capacity in your trucks alternator to go that route.
There always is a third option. Buy some ice! You can get dry ice at many grocery stores/butchers, it will last longer and is a lot colder.