Re: How many layers of glass to make a strong joint?
I think the way you want to join the plywood is fine. Just make sure the piece on the underside is at least 1 ft wide, giving 6" on each side of the joint. Use a water proof wood glue or construction adhesive. Use screws to draw the pieces together until the glue dries. Pre-drill the holes on the top piece so the screw just bites into the lower piece and pulls it up snug.
As far as the fiberglass, one or two layers of 6 oz should be fine. You are just trying to create a waterproof barrier on top of the ply, and the mat will just make a bumpy layer that will show through the 6 oz, and leave many air gaps or require lots of unecessary sanding to make it smooth. You are not trying to build up strength, just make a protective barrier. The 6oz will lay nice and smooth over the ply.