Agree with AllDodge. This is flange head bolt which is typically used in those applications and the fact that this one has that wasp waist indicates it was worn down over time > the bolt came slightly loose, and the vibrations of the pump / alt wore it down until someone replaced it. Check every single bolt associated with pump, alt, idler pulley, belt tensioner.
Question: do you have (or did you have) a lot of belt dust in line with the belt (dust pattern is like the belt is spinning off water and it also collects on block behind the belt)? Belt dust looks like fine back specs. This is an indication something wrong with the components the belt is turning (loose, out of line, rusted pulley, etc.)